作者:张建民; 王志武; 石秋芝金属配合物极谱法电位法稳定常数
摘要:0IntroductionTheexperimentalmethodsappliedinthefieldofdeterminationofmetalcomplexstabilityconstantsshouldbeclassifiedintotwoways—oneisanequilib鄄riumtechniqueandanotherisadynamictechnique[1].Theequilibriumtechnique,suchasglasselectrodepo鄄tentiometry(GEP),ionsensitiveorionselectiveelec鄄trodes(ISE),meansthattheconcentrationsofallspeciespresentinasamplearethesameinbulkaswellasatthesurfaceofasensorduringtheexperi鄄mentalprocess.ISEarefrequentlyusedinthefieldofametal鄄ligandequilibriumstudy[2~5]andwithrecentimprove...
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